The study of microscopic and macroscopic characteristics behaviour of melts and liquids during the cooling process at the different external influences permits to get the physical interpretation of the formation mechanism of non-crystalline materials including the consideration of their stability and nonequilibrity degree. In this report the results of investigation of the formation peculiarities of non-crystalline structures with the account of non-linear, synergetic effects are presented. In the interval of phase transition side by side with the thermal vibrations of atoms the heterophase fluctuations cause the essential role on the physical properties of non-crystalline materials. These heterophase fluctuations are the spatially distributed regions with distinguished from the initial matrix interaction character and bonds topology.
