A review of analytical, numerical and experimental investigations of melting and ensuing convection of phase change materials within enclosures with different shapes commonly used for thermal energy storage is presented. The common shapes of the containers being rectangular cavities, spherical capsules, tubes or cylinders (vertical and horizontal depending on orientation of gravity) and annular cavities are covered. Studies focusing on melting within rectangular cavities are categorized into two groups. The first one is melting due to isothermal heating on one or more boundaries, whereas the second is the constant heat flux-assisted melting. Moreover, constrained and unconstrained melting in both spherical and horizontal cylindrical containers were discussed. The effects of the concentric geometry and location of the heating source on melting in horizontal annular spaces are presented. The review concentrated on elucidating the heat transfer mechanisms (conduction and convection) during the multiple stages of the melting process and the effects of these mechanisms on the liquid–solid interface shape and its progress, melting rate, charging time of the storage system, etc. The strength of buoyancy driven-convection varies greatly with the dimensionless Rayleigh or Stefan numbers and depends somewhat on the location of heat source and imposed boundary condition. High dimensionless numbers and/or side position of the heat source ensure the dominant role of natural convection melting, otherwise conduction will be responsible for major melting within the container. Furthermore, the geometrical parameters such as the aspect ratio in rectangular containers and vertical cylindrical ones, diameter or radius in spherical capsules and horizontal cylindrical vessels, and eccentricity in annular cavities are reviewed. In addition, the parameters affecting the thermal behavior of the melting process in various enclosures, i.e. the Nusselt, Rayleigh, Stefan, Prandtl and Fourier numbers and are reviewed.
