The EMF study of caesiumborate melts containing 0-45mol% Cs20 is carried out over the temperature range 800-1300K. The complete set of thermodynamic properties of the melts is calculated being referred to the corresponding properties of pure oxides. The results obtained is discussed in terms of acid-base interaction of the components of the melts. A chemical structure of the melts is simulated on the basis of the ideal assiciated solution model.
Origin
Inst Silicate Chemistry Russian Academy Sciences
Journal Title
Proc 17Th Int Cong Glass, Beijing, Vol 3 October 1995 431-436
Sector
Special Glass
Class
S 1291