The Corrosion Of E-Glass Fibres In Complexing Organic Acids

This paper examines the leaching patterns of pyruvic acid, and relates this to similar patterns of oxalic, glyoxilic and malonic acids in a further attempt to clarify the mechanism of the corrosion process. It appears that these acids selectively leach boron to a greater extent than other cations, and as boron is part of the E-glass matrix rather than jut an interstitial ion, this would explain the means by which these relatively weak acids are able to corrode the glass fibres. It is well known that oxalic acid forms strong complexes with boron, and it is likely that other dicarboxilic acids or carboxylic acids with appropriately placed ligand groups (e.g. glyoxilic acid) will do likewise. This work presents a study of the rate of strength loss and the rate of leaching of cations from E-glass fibres with a particular emphasis on boron.

Author
R.L. Jones
Origin
Curtin University Of Technology, Australia.
Journal Title
Advanced Materials Research Vols 39-40 (2008) 311-316
Sector
Glass Fibre
Class
GF 574

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The Corrosion Of E-Glass Fibres In Complexing Organic Acids
Advanced Materials Research Vols 39-40 (2008) 311-316
GF 574
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