Contribution To The Drawing Of Annealing Schedules Based On Changes In The Structural State Of Glass

Having shown experimentally that the birefringence in glass after annealing depends mainly on its structural gradient, we conclude that annealing must be carried out in such a way that the glass is practically in structural equilibrium at any time; moreover, the final cooling must be started with a glass free from thermal/structural gradient. Studying thermal treatment of several glasses & working over small temp. ranges & taking care that the glass was completely stabilised at each stage, we have ascertained that in this way we got complete stabilisation in a time definitely shorter than that needed when stabilising either as a single temp. chosen in the lower part of the transformation range or by steps as pointed out by Winter-Klein. This process has been used for very dissimilar glasses & for thickness from 2-20cm, always with the same final result, i.e. the structural heterogeneity was not higher than one unit of the fifth decimal of the refractive index.//We have also found that when a glass undergoes partial heat treatment, a high degree of stabilisation may be obtained with a final birefringence much smaller than that obtained by classical annealing in the same time.

Author
B Daragan
Origin
Unknown
Journal Title
Iii Int.Cong.On Glass 1953, P411-425
Sector
Primary Papers
Class
PP 1427

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Contribution To The Drawing Of Annealing Schedules Based On Changes In The Structural State Of Glass
Iii Int.Cong.On Glass 1953, P411-425
PP 1427
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