High-Temperature Oxygen Sensors For Glass-Forming Melts

Electrochemical sensors are reported for the on-line measurement of oxygen partial pressures of oxidic glass-forming melts on a laboratory and technical scale. Based on the principle of solid electrolyte cells without transference, they are principally simple units. The extreme chemical and temperature conditions of their application, however, demanded extensive fundamental investigations and resulted in specific forms of reference and measuring electrodes, a thermodynamic procedure of verifying the correct functioning of such cells, and a method of measuring thermoelectric voltages of non-isothermal glass melts.